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Sea Fuel Farm

          Photosynthesis operates in fresh or salt water at 40 times the rate on land.  There are many simple plants that grow in any kind of water doubling their mass in 12 hours of sunlight if they get enough carbon dioxide and they make a protein rich material that can be dried and ground to be made into animal food pellets or consumed by bacteria to make butanol.

          Normal butanol or “n-butanol” the one with the hydroxyl at the end of the molecule and not on the second carbon atom or appended to the tertiary allotrope, is the one most common produced by the Clostridinium acetobutylicum bacillis.  This is the second oldest known industrial fermentation and it is the fuel of the future.

          Unlike ethanol n-butanol is not miscible in water.  When water is chilled to 0 Celsius 93% of all butanol in solution separates and floats on top of the vessel in which the mixture is held.  “Miscible” means the two molecules are totally compatible and this is due to polarity.  Water is a polar solvent.  Ethanol is weakly polar and butanol very weakly polar.  It separates from water when chilled.  In this system about 90% of the butanol will have come out of solution at the 4 degrees C temperature easily found in the seas or lakes sufficiently deep to have cold, 4 degree Celsius, water.  That is the point on the thermometer where water is most dense. Few lakes are deep enough or cold enough for this system so it will be more likely established in quiet ocean bays.

          The reaction vessel is a 100 foot long transparent polycarbonate plastic tube with a diameter of three feet.  It may be seamless like a noodle or welded together from a ten foot wide sheet.  The left top end has a tube that is used to introduce CO2 and draw finished butanol.  The right, or bottom, end has an operable valve to open to admit sea or lake water.  Ranks of the tubes are floated on the surface for sunlight with CO2 pumped into them to feed the algae and float the apparatus.

          In operation the tube is floating on the surface and produces algae to the point where it is so packed light will be blocked and photosynthesis will decline.  The pressure in the tube will increase to make the tube rigid and signal it is time to introduce bacteria and for the fermentation.  The  bacteria will work best in warmer water.  When the butanol reaches 35% of the fermentation mass the process will stop.  One end of the tube is sunk to make the tube vertical then the entire tube is lowered  to watter at four Celsius degrees where the butanol will separate.  When the separation has butanol in the top 32 feet of the tube the lower valve is opened and the finished product is drawn off.  Seawater from below enters the tube to replace the drawn butanol.          
     

          The volume of butanol removed will be about 32 gallons per tube. In ideal conditions the fermentation should take a few days, lowering and separation about one day and then the process is repeated.

          When the lower valve is opened to the sea to admit water and the butanol drawn off by pump  a conductivity switch stops the process when conductive sea water reaches the top.  The lower valve is then closed and the tube pulled to the surface for another cycle where algae and seawater are in the tube.  We only need to pump CO2  into the tube to promote photosynthesis and start the next cycle.

          A rank of 70 such tubes in a 100 foot on a side square would occupy one quarter acre and produce between 12,000 and 24,000 gallons of 100 octane motor fuel per year.  An ideal location for this system would be Baja California.  It is calm and easily serviced by sea or road from nearby major facilities in San Diego.  It is also in a desert area with virtually no overcast or rain.   An area 1/89th that of Baja California could make enough butanol to power every motor vehicle in the United States in 2008 if it were filled with these systems.

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